3-Hydroxypyridinium hydrogen chloranilate monohydrate
نویسندگان
چکیده
In the title salt hydrate, C(5)H(6)NO(+)·C(6)HCl(2)O(4) (-)·H(2)O, the three components are held together by O-H⋯O and N-H⋯O hydrogen bonds, as well as by C-H⋯O contacts, forming a double-tape structure along the c axis. Within each tape, the pyridinium ring and the chloranilate ring are almost coplanar, forming a dihedral angle of 2.35 (7)°.
منابع مشابه
Unique Electronic and Structural Properties of 1,4-Benzoquinones: Crystallochemistry of Alkali Chloranilate Hydrates*
The unique electronic and structural characteristics of 1,4-benzoquinones with possibilities for numerous interactions such as coordination, hydrogen bonding accompanied by proton and/or electron transfer, π-interactions, and redox activity, are used by nature to perform important biological reactions. In spite of their wide use in supramolecular chemistry for construction of functional materia...
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In the title compound, C(4)H(6)N(3) (+)·C(6)HCl(2)O(4) (-)·H(2)O, anions, cations and water mol-ecules are linked by inter-molecular O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonds into one-dimensional tapes along [111]. These tapes are further linked by weak Cl⋯Cl inter-actions [Cl⋯Cl = 3.394 (2) Å], forming sheets parallel to the (10) plane.
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In the crystal structure of the title salt, 3C(5)H(6)NO(+)·HSO(4) (-)·SO(4) (2-)·H(2)O, the hydrogen sulfate ion is linked to the sulfate ion by an O-H⋯O hydrogen bond. The hydrogen sulfate-sulfate anion is a hydrogen-bond acceptor for the three independent cations and the uncoordinated water mol-ecule, the hydrogen-bonding inter-actions giving rise to a three-dimensional hydrogen-bonded networ...
متن کاملBis(4-hydroxypyridinium) sulfate monohydrate
In the crystal structure of the title salt, 2C(5)H(6)NO(+)·SO(4) (2-)·H(2)O, one planar (r.m.s. deviation = 0.01 Å) cation is stacked approximately over the other [dihedral angle between planes = 8.6 (1)°]. The pyridinium and hydr-oxy H atoms are hydrogen-bond donor atoms to the O atoms of the sulfate anion; the cations, anions and water mol-ecules are consolidated into a three-dimensional netw...
متن کاملCrystal Structure of Lutidinium Chloranilates
The crystal structure of four lutidinium chloranilates, (CH3)2C6H3NH + C6HO4Cl2 , was determined by single crystal X-ray diffraction at room temperature. 2,4-lutidinium chloranilate (I): triclinic, P1̄ (#2), Z = 2, a = 11.401(2), b = 11.639(2), c = 5.1588(8) Å, = 91.899(15) , = 90.104(14) , and = 83.355(16) , 2,5-lutidinium chloranilate (II): monoclinic, P21/c (#14), Z = 4, a = 7.709(2), b = 11....
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009